Read full paper at:
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53197#.VLciWcnQrzE
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53197#.VLciWcnQrzE
ABSTRACT
YB-2
aviation polymethyl methacrylate (PMMA) is irradiated in a xenon arc
lamp weather resistance test chamber for 1620 hours. The tensile
strength, light transmittance, surface morphology, relative molecular
mass, infrared absorption spectrum and glass transition temperature (Tg)
of PMMA exposed in xenon arc lamp for different durations are tested
and characterized by universal testing machine, optical haze instrument,
scanning electronic microscopy (SEM), gel permeation chromatograph
(GPC), fourier transform infrared spectrometer (FT-IR) and differential
scanning calorimetry (DSC), so as to comprehensively analyze the
influence of xenon arc lamp irradiation on the performance of PMMA. The
results reveal that under the effect of 1620 hours xenon arc lamp
irradiation and periodic spraying water, the light transmittance and
glass transition temperature do not change significantly, and no new
chemical group is produced. After irradiated 360 hours, tiny cracks
occur in the surface of PMMA, indicating that they occur at a certain
degree of degradation, meanwhile, the main chain may be broken and the
relative molecular mass of surface of the material decreases. After
exposure of 720 hours, the tensile strength decreases about 30%.
KEYWORDS
Aviation Perspex, Xenon Arc lamp Irradiation, Relative Molecular Mass, Surface Morphology, Gel Permeation Chromatograph
Cite this paper
References
Meng, J. and Wang, Y. (2015) Effect of Xenon Arc Lamp Irradiation on Properties of Polymethyl Methacrylate for Aviation. Open Journal of Organic Polymer Materials, 5, 23-29. doi: 10.4236/ojopm.2015.51002.
| [1] | Chinese Aviation Materials Manual Editorial Board (2002) Chinese Aviation Materials Manual, Plastics Transparent materials Insulating Materials. Vol. 7, China Standards Press, Beijing, 223. |
| [2] | Li, X.G., Gao, J., Zhang, S.P., et al. (2011) The Aging Principle and Mechanism of High Polymer Material in Natural Environment. Science Press, Beijing, 7-8, 21-104. |
| [3] | Liu, H.Y., Li, X.M. and Wang, H.B. (2011) Research on Accelerated Weathering Test Technique of Perspex. Equipment Environmental Engineering, 8, 83-86. |
| [4] | Chang,
T.C., Yu, P.Y., Hong, Y.S., et al. (2002) Effect of Phenolic Phosphate
Antioxidant on the Thermo-Oxidative Degradation of PMMA. Polymer
Degradation & Stablization, 77, 29-34. http://dx.doi.org/10.1016/S0141-3910(02)00076-9 |
| [5] | Darowicki, K., Szocinski, M., Schaefer, K., et al. (2011) Investigation of Morphological and Electrical Properties of the PMMA Coating upon Exposure to UV Irradiation based on AFM Studies. Progress in Organic Coatings, 71, 65-71. http://dx.doi.org/10.1016/j.porgcoat.2010.12.012 |
| [6] | Motaung,
T.E., Luyt, A.S., Bondioli, F., et al. (2012) PMMA-Titania
Nanocomposites: Properties and Thermal Degradation Behavior. Polymer
Degradation & Stablization, 97, 1325-1333. http://dx.doi.org/10.1016/j.polymdegradstab.2012.05.022 |
| [7] | Hou, Y.L., Qiao, Q.J. and Li, H.C. (2006) An Equivalent Relationship of the Perspex Fatigue Life between the Natural and Artificial Aging. Journal of Henan University (Natural Science), 36,118-122. |
| [8] | Ma, L.T., Chen, X.W. and Su, B. (2008) Aging Mechanism of Perspex under the Typical Environment. Physical Testing and Chemical Analysis Part A: Physical Testing, 44, 64-67. |
| [9] | He, M.J., Zhang, H.D., Chen, X.W., et al. (2008) High Polymer Physics. Fudan University Press, Shanghai, 114-122, 206-208. |
| [10] | Zhang, L.Y. (1999) The Progress and Application of Transparent Polymer Materials. New Chemical Materials, 27, 37-40. |
| [11] | Zhong, S.Y., Xu, Q.W. and Wang, G.S. (2002) Polymer Degradation and Stabilization. Chemical Industry Press, Beijing, 94-96. |
| [12] | Zhu, Q.Q. and Feng, L.X. (1995) Optically Transparent Macromolecule Materials. Polymer Material Science and Engineering, 11, 1-6. |
| [13] | Chen, X.W., Zhang, T.J. and Liu, S.H. (2009) Accelerated Ageing Behavior of PMMA under Hygrothermal Air and Water Conditions. Failure Analysis and Prevention, 4, 193-195. eww150115lx |
评论
发表评论