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目前显示的是标签为“Gas Phase”的博文

Vibrational Nonequilibrium in the Hydrogen-Oxygen Reaction at Different Temperatures

Read full paper at: http://www.scirp.org/journal/PaperInformation.aspx?PaperID=51088#.VFMhOGfHRK0 Author(s) Oleg V. Skrebkov * Affiliation(s) Theoretical Department, Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia . ABSTRACT A theoretical model of chemical and vibrational kinetics of hydrogen oxidation is suggested based on the consistent account for the vibrational nonequilibrium of HO 2 radical which forms in result of bimolecular recombination H + O 2 = HO 2 in the vibrationally excited state. The chain branching H + O 2 = O + OH and inhibiting H + O 2 + M = HO 2 + M formal reactions are considered (in the terms of elementary processes) as a general multi-ch...