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Theorem of Necessity and Sufficiency of Stable Equilibrium for Generalized Potential Equality between System and Reservoir

Read full paper at: http://www.scirp.org/journal/PaperInformation.aspx?PaperID=52198#.VIj89snQrzE Author(s) Pierfrancesco Palazzo * Affiliation(s) Technip, Rome, Italy . ABSTRACT The literature reports that equality of temperature, equality of potential and equality of pressure between a system and a reservoir are necessary conditions for the stable equilibrium of the system-reservoir composite or, in the opposite and equivalent logical inference, that stable equilibrium is a sufficient condition for equality. The aim and the first novelty of the present study is to prove that equality of temperature, potential and pressure is also a sufficient condition for stable equilibrium, in addition to necessity, implying ...