Cost Effective Adsorption of Aluminium and Iron from Synthetic and Real Wastewater by Rice Hull Activated Carbon (RHAC)
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http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53266#.VLiDt8nQrzE
Affiliation(s)
1Chemistry Department, Faculty of science, Cairo University, Cairo, Egypt.
2RCFF, Agricultural Research Center, Giza, Egypt.
3Holding Company for Water and Wastewater, Greater Cairo Water Company, Cairo, Egypt.
2RCFF, Agricultural Research Center, Giza, Egypt.
3Holding Company for Water and Wastewater, Greater Cairo Water Company, Cairo, Egypt.
ABSTRACT
The
adsorption of aluminium(III) and iron(III) ions from their single and
binary systems, by RHAC was investigated in a batch system. The
activated carbon prepared from rice hulls was characterized by scanning
electron microscopy and Fourier transformation infrared techniques.
Batch adsorption experiments were performed under different operating
conditions including pH (2 - 5), adsorbent dosage (0.5 - 2.0 g/l),
initial ion concentration (5 - 100 mg/l), and contact time (30 - 240
min). The equilibrium time for maximum ions removal was found to be 180
min in single and binary ions systems. The kinetics of adsorption was
evaluated using the pseudo-first order, pseudo-second order and Elovich
kinetic models. The Langmuir, Freundlich and Temkin equilibrium models
were applied to the adsorption experimental data. Real wastewater
samples were collected from different locations to investigate the
efficiency of rice hull activated carbon in treating real samples. The
real wastewater samples were treated with the activated carbon prepared
from rice hulls and a commercial activated carbon. The results showed
that the activated carbon prepared in the present work was more
efficient in the removal of aluminium and iron from real wastewater as
compared to the commercial activated carbon which is more advantageous
considering both economics and environmental parameters.
Cite this paper
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Aluminium and Iron from Synthetic and Real Wastewater by Rice Hull
Activated Carbon (RHAC). American Journal of Analytical Chemistry, 6, 71-83. doi: 10.4236/ajac.2015.61007.
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