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Author(s)
Nano-sized particles have got a focus of great
interest for the past decade. These ultrafine particles can have an
effect in multiple ways on concrete technology. Although most of the
effects of nanoparticles are desired, a huge surface area introduced by
nanoparticles also incorporates negative effects, such as loss of
workability and safety aspects. Agglomeration of nano-sized particles by
spray-drying is one potential method to overcome the negative effects.
In this study, ultra-fine material was dispersed and agglomerated
successfully. Agglomerate structure was analyzed and performance was
evaluated with mortar samples. Agglomerated nano-sized material had
micron-sized inner porosity, which enabled water penetration into the
agglomerates. In water exposure, agglomerates did not dissolve although
some of binder glue and dispersing agent leaked out. Water penetration
and organic material leaking enabled high reactivity and workability of
the agglomerated nanoparticles. In spite of the high reactivity of
agglomerated nanoparticles, slightly lower final compression strengths
were observed with agglomerated ultrafine particles. The results of this
study can be used in concrete technology when further developing
admixture technologies and recipe designs. The negative side-effects of
the agglomerated nanoparticles can be overcome and accounted for within
application areas.
KEYWORDS
Cite this paper
Vehmas, T. , Kanerva, U. and Holt, E. (2014)
Spray-Dry Agglomerated Nanoparticles in Ordinary Portland Cement Matrix.
Materials Sciences and Applications, 5, 837-844. doi: 10.4236/msa.2014.512084.
| [1] |
Maynard, A.D. (2006) Nanotechnology: Assessing the Risks. Nano Today, 1, 22-33. http://dx.doi.org/10.1016/S1748-0132(06)70045-7 |
| [2] |
Maynard, A.D. (2007)
Nanotechnology: The Next Big Thing, or Much Ado about Nothing? Annals of
Occupational Hygiene, 51, 1-12. http://dx.doi.org/10.1093/annhyg/mel071 |
| [3] |
Sanchez, F. and Sobolev, K.
(2010) Nanotechnology in Concrete—A Review. Construction and Building
Materials, 24, 2060-2071. http://dx.doi.org/10.1016/j.conbuildmat.2010.03.014 |
| [4] |
Pacheco-Torgal, F. and Jalali,
S. (2011) Nanotechnology: Advantages and Drawbacks in the Field of
Construction and Building Materials. Construction and Building
Materials, 25, 582-590. http://dx.doi.org/10.1016/j.conbuildmat.2010.07.009 |
| [5] |
Li, G.Y., Wang, P.M. and Zhao,
X. (2005) Mechanical Behavior and Microstructure of Cement Composites
Incorporating Surface-Treated Multi-Walled Carbon Nanotubes. Carbon, 43,
1239-1245. http://dx.doi.org/10.1016/j.carbon.2004.12.017 |
| [6] |
Li, G.Y., Wang, P.M. and Zhao,
X. (2007) Pressure-Sensitive Properties and Microstructure of Carbon
Nanotube Reinforced Cement Composites. Cement and Concrete Composites,
29, 377-382. http://dx.doi.org/10.1016/j.cemconcomp.2006.12.011 |
| [7] |
Ibusuki, T. and Takeuchi, K.
(1994) Removal of Low Concentration Nitrogen Oxides through
Photoassisted Heterogeneous Catalysis. Journal of Molecular Catalysis,
88, 93-102. http://dx.doi.org/10.1016/0304-5102(93)E0247-E |
| [8] |
Ballari, M.M., Hunger, M.,
Hasken, G. and Brouwers, H.J.H. (2010) NOx Photocatalytic Degradation
Employing Concrete Pavement Containing Titanium Dioxide. Applied
Catalysis B: Environmental, 95, 245-254. http://dx.doi.org/10.1016/j.apcatb.2010.01.002 |
| [9] | Sato, T. and Diallo, F. (2010) Seeding Effect of Nano-CaCO3 on the Hydration of Tricalcium Silicate. Journal of the Transportation Research Record, 2141, 61-67. |
| [10] | Mondal, P., Shah, S., Marks, L. and Gaitero, J. (2010) Comparative Study of the Effects of Microsilica and Nanosilica in Concrete. Transportation Research Record, 2141, 6-9. |
| [11] |
Cassar, L. (2004) Photocatalysis
of Cementitious Materials: Clean Buildings and Clean Air. MRS Bulletin,
5, 328-331. http://dx.doi.org/10.1557/mrs2004.99 |
| [12] | Stark, J., Moser, B. and Bellmann, F. (2007) Nucleation and Growth of C-S-H Phases on Mineral Admixtures. Advances in Construction Materials, 531-538. |
| [13] |
Blyszko, J., Kiernozycki, W.,
Guskos, N., Zolnierkiewicz, G., Typek, J., Narkiewicz, U. and Podsiadly,
M. (2008) Study of Mechanical Properties of Concrete with Low
Concentration of Magnetic Nanoparticles. Journal of Non Crystalline
Solids, 354, 4515-4518. http://dx.doi.org/10.1016/j.jnoncrysol.2008.06.101 |
| [14] |
Nazari, A. and Riahi, S. (2010)
Assessment of the Effects of Fe2O3 Nanoparticles on Water Permeability,
Workability, and Setting Time of Concrete. Journal of Composite
Materials, 45, 923-930. http://dx.doi.org/10.1177/0021998310377945 |
| [15] |
Donaldson, K., Stone, V.,
Clouter, A., Renwick, L. and MacNee, W. (2001) Ultrafine Particles.
Occupational and Environmental Medicine, 58, 211-216. http://dx.doi.org/10.1136/oem.58.3.211 |
| [16] | Shaw, F. and Andrews, M. (1997) Spray Drying, Carbide, Nitride and Boride Materials Synthesis and Processing. Chapman & Hall, London. |
| [17] | Harris, D.C. (2003) Quantitative Chemical Analysis. 6th Edition, W.H. Freeman and Company, New York. |
| [18] |
TCE1 (1997) Adiabatic and
Semi-Adiabatic Calorimetry to Determine the Temperature Increase in
Concrete Due to Hydration Heat of the Cement. Materials and Structures,
30, 451-464. http://dx.doi.org/10.1007/BF02524773 |
| [19] | Darr, G.M. and Ludwig, U. (1973) Determination of Permeable Porosity. Materials and Structures, 6, 185. |
| [20] |
Rostasy, F.S., Weib, R. and
Wiedemann, G. (1980) Changes of Pore Structure of Cement Mortar due
Temperature. Cement and Concrete Research, 10, 157-164. http://dx.doi.org/10.1016/0008-8846(80)90072-1 |
| [21] |
Kumar, R. and Bhattacharjee, B.
(2003) Porosity, Pore Size Distribution and In-Situ Strength of
Concrete. Cement and concrete research, 33, 155-164. http://dx.doi.org/10.1016/S0008-8846(02)00942-0. eww141023lx |
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