In-Situ Measurements of the Photoconductivity of Multi-Layered Organic Photovoltaic Devices Using Impedance Spectroscopy
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http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53662#.VM8paizQrzE
Affiliation(s)
1Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, Japan.
2Advanced Technology Research Laboratories, Idemitsu Kosan Co., Ltd., Sodegaura, Japan.
3Research Center for Photovoltaic Technologies, AIST, Tsukuba, Japan.
2Advanced Technology Research Laboratories, Idemitsu Kosan Co., Ltd., Sodegaura, Japan.
3Research Center for Photovoltaic Technologies, AIST, Tsukuba, Japan.
ABSTRACT
In-situ
impedance spectroscopy (IS) observations of the photoconductivity of
the carriers induced by photo-irradiation in organic hetero-junction
structured photovoltaic devices are presented. In the IS measurements,
the externally applied voltage and the dependence of the light intensity
applied to the device were investigated. Analysis of the frequency
characteristics which was measured by changing the light intensity shows
there is a proportional relationship between the changes in the
conductivities of the two components. The mobilities of the CuPc and C60
layers were calculated from the conductivities and were in the orders
of 10﹣4 and 10﹣3 cm2/Vs, respectively.
Cite this paper
References
Maeda, R. , Tokairin, H. , Takahashi, J. and Yoshida, Y. (2015) In-Situ Measurements of the Photoconductivity of Multi-Layered Organic Photovoltaic Devices Using Impedance Spectroscopy. Advances in Materials Physics and Chemistry, 5, 47-52. doi: 10.4236/ampc.2015.52007.
| [1] | Campbell,
A.J., Bradley, D.D.C. and Lidzey, D.G. (1997) Space-Charge Limited
Conduction with Traps in Poly (phenylene vinylene) Light Emitting
Diodes. Journal of Applied Physics, 82, 6326-6342. http://dx.doi.org/10.1063/1.366523 |
| [2] | Brütting,
W., Riel, H., Beierlein, T. and Riess, W. (2001) Influence of Trapped
and Interfacial Charges in Organic Multilayer Light-Emitting Devices.
Journal of Applied Physics, 89, 1704. http://dx.doi.org/10.1063/1.1332088 |
| [3] | Martens,
H.C.F., Pasveer, W.F., Brom, H.B., Huiberts, J.N. and Blom, P.W.M.
(2001) Crossover from Space-Charge-Limited to Recombination-Limited
Transport in Polymer Light-Emitting Diodes. Physical Review B, 63,
Article ID: 125328. http://dx.doi.org/10.1103/PhysRevB.63.125328 |
| [4] | Nguyen,
N.D., Schmeits, M. and Loebl, H.P. (2007) Determination of
Charge-Carrier Transport in Organic Devices by Admittance Spectroscopy:
Application to Hole Mobility in α-NPD. Physical Review B, 75, Article
ID: 075307. http://dx.doi.org/10.1103/PhysRevB.75.075307 |
| [5] | Okachi,
T., Nagase, T., Kobayashi, T. and Naito, H. (2008) Determination of
Charge-Carrier Mobility in Organic Light-Emitting Diodes by Impedance
Spectroscopy in Presence of Localized States. Japanese Journal of
Applied Physics, 47, 8965. http://dx.doi.org/10.1143/JJAP.47.8965 |
| [6] | Garcia-Belmonte,
G., Munara, A., Bareaa, E.M., Bisquerta, J., Ugarteb, I. and Paciosb,
R. (2008) Charge Carrier Mobility and Lifetime of Organic Bulk
Heterojunctions Analyzed by Impedance Spectroscopy. Organic Electronics,
9, 847-851. http://dx.doi.org/10.1016/j.orgel.2008.06.007 |
| [7] | Jorgensen,
M., Norrman, K. and Krebs, F.C. (2008) Stability/Degradation of Polymer
Solar Cells. Solar Energy Materials and Solar Cells, 92, 686-714. http://dx.doi.org/10.1016/j.solmat.2008.01.005 |
| [8] | Ahles,
M., Schmechel, R. and von Seggern, H. (2004) N-Type Organic
Field-Effect Transistor Based on Interface- Doped Pentacene. Applied
Physics Letters, 85, 4499. http://dx.doi.org/10.1063/1.1818737 |
| [9] | Torres,
I. and Taylor, D.M. (2005) Interface States in Polymer
Metal-Insulator-Semiconductor Devices. Journal of Applied Physics, 98,
Article ID: 073710. http://dx.doi.org/10.1063/1.2081109 |
| [10] | Redecker,
M., Bradley, D.D.C., Inbasekaran, M. and Woo, E.P. (1998) Nondispersive
Hole Transport in an Electroluminescent Polyfluorene. Applied Physics
Letters, 73, 1565-1567. http://dx.doi.org/10.1063/1.122205 |
| [11] | Redecker,
M., Bradley, D.D.C., Inbasekaran, M. and Woo, E.P. (1999) Mobility
Enhancement through Homogeneous Nematic Alignment of a
Liquid-Crystalline Polyfluorene. Applied Physics Letters, 74, 1400-1402.
http://dx.doi.org/10.1063/1.123563 |
| [12] | Poplavskyy,
D., Nelson, J. and Bradley, D.D.C. (2003) Ohmic Hole Injection in
Poly(9,9-dioctylfluorene) Polymer Light-Emitting Diodes. Applied Physics
Letters, 83, 707-709. http://dx.doi.org/10.1063/1.1596722 |
| [13] | Poplavskyy,
D. and Nelson, J. (2003) Nondispersive Hole Transport in Amorphous
Films of Methoxy-Spirofluorene-Arylamine Organic Compound. Journal of
Applied Physics, 93, 341-346. http://dx.doi.org/10.1063/1.1525866 |
| [14] | Poplavskyy,
D., Su, W.C. and So, F. (2005) Bipolar Charge Transport, Injection, and
Trapping Studies in a Model Green-Emitting Polyfluorene Copolymer.
Journal of Applied Physics, 98, Article ID: 014501. http://dx.doi.org/10.1063/1.1941482 |
| [15] | Khan,
R.U.A., Bradley, D.D.C., Webster, M.A., Auld, J.L. and Walker, A.B.
(2004) Degradation in Blue-Emitting Conjugated Polymer Diodes Due to
Loss of Ohmic Hole Injection. Applied Physics Letters, 84, 921-923. http://dx.doi.org/10.1063/1.1645982 |
| [16] | Tse,
S.C., Fong, H.H. and So, S.K. (2003) Electron Transit Time and Reliable
Mobility Measurements from Thick Film Hydroxyquinoline-Based Organic
Light-Emitting Diode. Journal of Applied Physics, 94, 2033-2037. http://dx.doi.org/10.1063/1.1589175 |
| [17] | Saeki,
A., Tsuji, M. and Seki, S. (2011) Direct Evaluation of Intrinsic
Optoelectronic Performance of Organic Photovoltaic Cells with Minimizing
Impurity and Degradation Effects. Advanced Energy Materials, 1,
661-669. http://dx.doi.org/10.1002/aenm.201100143 |
| [18] | Saeki,
A., Yoshikawa, S., Tsuji, M., Koizumi, Y., Ide, M., Vijayakumar, C. and
Seki, S. (2012) A Versatile Approach to Organic Photovoltaics
Evaluation Using White Light Pulse and Microwave Conductivity. Journal
of the American Chemical Society, 134, 19035-19042. http://dx.doi.org/10.1021/ja309524f |
| [19] | Azuma,
H., Asada, K., Kobayashi, T. and Naito, H. (2006) Fabrication of α- and
β-phase Poly(9,9-dioctylfluorene) Thin Films. Thin Solid Films, 509,
182-184. http://dx.doi.org/10.1016/j.tsf.2005.09.032 eww150202lx |
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