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http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53765#.VNHUpizQrzE
ABSTRACT
The
present study is dealing with the corrosion of copper coated with
nanocrystalline nickeltungsten coating. Different plating bath
compositions and conditions were used in order to produce
nickel-tungsten coatings of different tungsten content 30%, 40% and 50%
wt, with a thickness of 20 μm. The corrosion resistance of
nickel-tungsten alloy coated copper was examined by a potentiodynamic
polarisation technique in NaCl solution (0.03 M, 0.3 M and 1 M) as a
function of pH (3, 7, 10) and temperature (7°C, 30°C, 40°C) of the
solution. It has been found that the pH value did not seem to affect the
corrosion behaviour of the coated specimen remarkably, while the
increase of solution temperature increased the corrosion rate of the
coated copper specimen. It was finally confirmed that the corrosion
products mainly consisted of tungsten and nickel oxides.
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