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http://www.scirp.org/journal/PaperInformation.aspx?PaperID=53340#.VL3KpyzQrzE
ABSTRACT
Egypt is bordered by coastal sea2450 km, while incident solar radiation is in the order of magnitudes of 1900-2200 W/m2
in that area of the world. The present work is aimed to assess the
hydrogen production from the solar-hydrogen system composed of
photovoltaic cell motivated by solar energy and supplies electricity to
alkali electrolyzer. The electrolyzer uses sea and Nile water as
electrolytes. Indoor tests are done to identify the optimum
concentration ratio of the sea water to produce hydrogen. Experimental
results showed that stand-alone sea water gives a higher production
rate. The results of the outdoor tests revealed the need for about seven
units of electrolyzer working with the sea water to produce the same
amount of hydrogen that KOH solution electrolyte would provide. However,
the efficiency of solar-hydrogen units working with the sea water gives
a lower constant efficiency of about 0.13%, followed by
Photovoltaic/electrolyzer unit using Nile water of approximately 0.005%.
The KOH solution electrolyte provides an efficiency of approximately 8%
at solar noon. The sea water is recommended to be used instead of KOH
solution in all coming electrolyzers.
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References
Shedid, M. and Elshokary, S. (2015) Hydrogen Production from an Alkali Electrolyzer Operating with Egypt Natural Resources. Smart Grid and Renewable Energy, 6, 14-25. doi: 10.4236/sgre.2015.61002.
| [1] | McDonall,
W. and Eames, M. (2006) Forecast, Scenarios, Visions, Backcasts and
Roadmaps to the Hydrogen Economy: A Review of the Hydrogen Futures
Literature. Energy Policy, 34, 1236-1250. http://dx.doi.org/10.1016/j.enpol.2005.12.006 |
| [2] | Envestra Limited (2010) About Natural Gas. http://www.natural-gas.com.au/about/references.html |
| [3] | ForestBioEnergy (2010) Sustainable Forestry for Bioenergy and Biobased Products. Energy Basics. Fact Sheet 5.8. |
| [4] | Information and Decision Support Center (IDSC) (2014) Geographical Location. http://www.eip.gov.eg/AboutEgypt/GeoInfo.aspx |
| [5] | Turner, J.A. (2004) Sustainable Hydrogen Production. Science, 305, 972-974. |
| [6] | Zavieh, A.H. (2011) Optimization and Modeling of Electrode Structure and Composition for Novel PEM Water Electrolyser MEAs. Norwegian University of Science and Technology, Norway. |
| [7] | Agbossou, K., Kolhe, M., Hamelin, J. and Bose, T.K. (2004) Performance of a Stand-Alone Renewable Energy System Based on Energy Storage as Hydrogen. IEEE Transactions on Energy Conversion, 19, 633-640. |
| [8] | Guo,
W.L., Li, L., Li, L.L., Tian, S., Liu, S.L. and Wu, Y.P. (2011)
Hydrogen Production via Electrolysis of Aqueous Formic Acid Solutions.
International Journal of Hydrogen Energy, 38, 9415-9419. http://dx.doi.org/10.1016/j.ijhydene.2011.04.127 |
| [9] | Pregger,
T., Graf, D., Krewitt, W., Sattler, C., Roeb, M. and Moller, S. (2009)
Prospects of Solar Thermal Hydrogen Production Processes. International
Journal of Hydrogen Energy, 34, 4256-4267. http://dx.doi.org/10.1016/j.ijhydene.2009.03.025 |
| [10] | Charvin,
P., Stéphane, A., Florent, L. and Gilles, F. (2008) Analysis of Solar
Chemical Processes for Hydrogen Production from Water Splitting
Thermochemical Cycles. Energy Conversion and Management, 49, 1547-1556. http://dx.doi.org/10.1016/j.enconman.2007.12.011 |
| [11] | Santarelli,
M. and Macagno, S. (2004) A Thermoeconomic Analysis of a PV-Hydrogen
System Feeding the Energy Requests of a Residential Building in an
Isolated Valley of the Alps. Energy Conversion and Management, 45,
427451. http://dx.doi.org/10.1016/S0196-8904(03)00156-0 |
| [12] | Ahmad, G.E. and Shenawy, E.T.E. (2006) Optimized Photovoltaic System for Hydrogen Production. Renewable Energy, 31, 1043-1054. http://dx.doi.org/10.1016/j.renene.2005.05.018 |
| [13] | El Shenawy, E.T. and Hamdy, H. (2012) Annual Performance of a Photovoltaic Hydrogen Electrolyzer System in Egypt. The Pacific Rim Energy and Sustainability Congress, Hiroshima, 6-9 August 2012. |
| [14] | Wang, Z., Roberts, R.R., Naterer, G.F. and Gabriel, K.S. (2012) Comparison of Thermochemical, Electrolytic, Photoelectrolytic and Photochemical Solar-to-Hydrogen Production Technologies. International Journal of Hydrogen Energy, 30, 1-15. |
| [15] | Ramadan, A., El-Shenawy, E., Dayem, A.A. and Eid, S.A. (2008) Optimization of PV-Hydrogen Electrolyzes System. 3rd International Conference on Engineering Science & Technology, Cairo. |
| [16] | Chennouf,
N., Settou, N., Negrou, B., Bouziane, K. and Dokkar, B. (2012)
Experimental Study of Solar Hydrogen Production Performance by Water
Electrolysis in the South of Algeria. Energy Procedia, 18, 1280-1288. http://dx.doi.org/10.1016/j.egypro.2012.05.145 |
| [17] | See,
D.M. and White, R.E. (1997) Temperature and Concentration Dependence of
the Specific Conductivity of Concentrated Solutions of Potassium
Hydroxide. Journal of Chemical & Engineering Data, 42, 1266-1268. http://dx.doi.org/10.1021/je970140x |
| [18] | Fatouh, M., Shedid, M.H. and Elshokary, S. (2013) Effect of Operating and Geometric Parameters on Hydrogen Production from an Alkali Electrolyzer. International Journal on Power Engineering and Energy (IJPEE), 4, 395-399. |
| [19] | Ibrahim,
A. (2011) Analysis of Electrical Characteristics of Photovoltaic Single
Crystal Silicon Solar Cells at Outdoor Measurements. Smart Grid and
Renewable Energy, 2, 169-175. http://dx.doi.org/10.4236/sgre.2011.22020 |
| [20] | Da
Silva, E.P., Marin Neto, A.J., Ferreira, P.F.P., Camargo, J.C.,
Apolinário, F.R. and Pinto, C.S. (2005) Analysis of Hydrogen Production
from Combined Photovoltaics, Wind Energy and Secondary Hydroelectricity
Supply in Brazil. Solar Energy, 78, 670-677. http://dx.doi.org/10.1016/j.solener.2004.10.011 |
| [21] | Zeng, K. and Zhang, D. (2010) Recent Progress in Alkaline Water Electrolysis for Hydrogen Production and Applications. Progress in Energy and Combustion Science, 36, 307-326. |
| [22] | Lenntech (2014) Composition of Seawater. http://www.lenntech.com/composition-seawater.htm eww150120lx |
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