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Electric Field of the Ocean Induced by Diffusion

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ABSTRACT
The equations for gradient of electric field in seawater induced by gradients of salinity, temperature and pressure were developed by means of non-equilibrium thermodynamics. Extrathermodynamic assumptions and accepted chemical model of seawater permit to carry out numerical calculations of electric field caused by diffusion, thermodiffusion and barodiffusion for realistic hydrophysical structure of the ocean. It is shown that contribution of barodiffusion into electric field of the ocean is almost constant (about -3 × 10-7 V/M). This magnitude can be ignored in many cases because it is too small. However natural salinity and temperature gradients significantly impact into electric field of the ocean.
 
Cite this paper
Tishchenko, P. (2015) Electric Field of the Ocean Induced by Diffusion. Journal of Electromagnetic Analysis and Applications, 7, 10-18. doi: 10.4236/jemaa.2015.71002.
 
References
[1]Palshin, N.A., Vanyan, L.L. and Kaikkonen, P. (1996) On-Shore Amplification of the Electric Field Induced by a Coastal Sea Current. Physics of the Earth and Planetary Interiors, 94, 269-273.
http://dx.doi.org/10.1016/0031-9201(95)03098-0
 
[2]Palshin, N.A. (1996) Oceanic Electromagnetic Studies: A Review. Surveys in Geophysics, 17, 455-491.
http://dx.doi.org/10.1007/BF01901641
 
[3]Longuet-Higgins, M.S., Stern, M.E. and Stommel, H. (1954) The Electrical Field Induced by Ocean Currents and Waves with Applications to Method of Towed Electrodes. Physical Oceanography and Meteorology, 13, 37.
 
[4]Cox, C. (1980) Electromagnetic Induction in the Oceans and Inferences of the Constitution of the Earth. Surveys in Geophysics, 4, 137-156.
http://dx.doi.org/10.1007/BF01452963
 
[5]Semenchenko, V.K. (1941) Physical Theory of the Solutions. Leningrad, Moscow. (In Russian)
 
[6]Tishchenko, P.Ya. (1984) Contribution of Diffusion Processes into Formation of Electric Field of the Ocean. Dokladi Akademii Nauk, 279, 1234-1238. (In Russian)
 
[7]Tishchenko, P.Ya. (1991) EMF Method for Measurements of the Electric Field in the Ocean. VINITI, Moscow, No. 165-B91. (In Russian)
 
[8]De Groot, S.R. and Mazur, P. (1962) Non-Equilibrium Thermodynamics. North-Holland Publishing Co., Amsterdam.
 
[9]Kirkwood, J.G., Baldwin, R.L., Dunlop, P.J., Gosing, L.J. and Kegeles, G. (1960) Flow Equations and Frames of Reference for Isothermal Diffusion in Liquids. Journal of Chemical Physics, 33, 1505-1513.
http://dx.doi.org/10.1063/1.1731433
 
[10]Agar, J.N. (1963) Thermogalvanic Cells. In: Delahay, P., Ed., Advances in Electrochemistry and Electrochemical Engineering, Interscience, New York, 31-120.
 
[11]De Groot, S.R. (1951) Thermodynamics of Irreversible Processes. North-Holland Publishing Comp., Amsterdam.
 
[12]DOE (1994) Handbook of Methods for the Analysis of the Various Parameters of the Carbon Dioxide System in Sea water. Version 2, Dickson, A.G. and Goyet, C., Eds., ORNL/CDIAC-74, Oak Ridge, Tennessee.
 
[13]Poisson, A., Perie, M., Perie, J. and Chemla, M. (1979) Individual Equivalent Conductances of the Major Ions in Seawater. Journal of Solution Chemistry, 8, 377-394.
http://dx.doi.org/10.1007/BF00646790
 
[14]Pitzer, K.S. (1973) Thermodynamics of Electrolytes. I. Theoretical Basis and General Equations. Journal of Physical Chemistry, 77, 268-277.
http://dx.doi.org/10.1021/j100621a026
 
[15]Pitzer, K.S. (1991) Ionic Interaction Approach: Theory and Data Correlation. In: Pitzer, K.S., Ed., Activity Coefficients in Electrolyte Solutions, CRC Press, Roca Raton, 75-153.
 
[16]Clegg, S.L. and Whitfield, M. (1991) Activity Coefficients in Natural Waters. In: Pitzer, K.S., Ed., Activity Coefficients in Electrolyte Solutions, CRC Press, Roca Raton, 279-434.
 
[17]Tishchenko, P., Hensen, C., Wallmann, K. and Wong, C.S. (2005) Calculation of the Stability and Solubility of Methane Hydrate in Seawater. Chemical Geology, 219, 37-52.
http://dx.doi.org/10.1016/j.chemgeo.2005.02.008
 
[18]Poisson, A. and Chanu, J. (1980) Semi-Empirical Equations for the Partial Molar Volumes of Some Ions in Water and in Seawater. Marine Chemistry, 8, 289-298.
http://dx.doi.org/10.1016/0304-4203(80)90018-3
 
[19]Fofonoff, N.P. and Millard, R.C. (1983) Algorithms for Computation of Fundamental Properties of Seawater. UNESCO, Paris.
 
[20]De Bethune, A.J. and Daley, H.O. (1969) The Thermal Temperature Coefficient of the Calomel Electrode Potential between 0°C and 70°C. II. Thermodynamic Results—The Moving and Transport Entropies and Heat Capacities of Aqueous Chloride Salines and Their Ions. Journal of the Electrochemical Society, 116, 1395-1401.
http://dx.doi.org/10.1149/1.2411532
 
[21]Kajmakov, E.A. and Varshavskaja, N.L. (1966) Measurements of Transference Numbers in Aqueous Solution Electrolytes. Uspekhi Khimii, 35, 201-228. (In Russian)
 
[22]Aguilella, V.M., Mafe, S. and Pellicer, J. (1987) On the Nature of the Diffusion Potential Derived from Nernst-Planck Flux Equations by Using the Electroneutrality Assumption. Electrochimica Acta, 32, 483-488.
http://dx.doi.org/10.1016/0013-4686(87)85018-1
 
[23]Hafemann, D.R. (1965) Charge Separation in Liquid Junction. Journal of Physical Chemistry, 69, 4226-4231.
http://dx.doi.org/10.1021/j100782a027
 
[24]Sasai, Y., Uyeshima, M., Zlotnicki, J., Utada, H., Kagiyama, T., Hashimoto, T. and Takahashi, Y. (2002) Magnetic and Electric Field Observations during the 2000 Activity of Miyake-Jima Volcano, Central Japan. Earth and Planetary Science Letters, 203, 769-777.
http://dx.doi.org/10.1016/S0012-821X(02)00857-9
 
[25]Nobes, D.C. (1996) Troubled Waters: Environmental Applications of Electrical and Electromagnetic Methods. Surveys in Geophysics, 17, 393-454.
http://dx.doi.org/10.1007/BF01901640
 
[26]Poisson, A. and Chanu, J. (1976) Partial Molal Volumes of Some Major Ions in Seawater. Limnology and Oceanography, 21, 853-861.
http://dx.doi.org/10.4319/lo.1976.21.6.0853
 
[27]Millero, F.J. and Pierrot, D. (1988) A Chemical Equilibrium Model for Natural Waters. Aquatic Geochemistry, 4, 153-199.
http://dx.doi.org/10.1023/A:1009656023546
 
[28]Miller, D.G. (1956) Thermodynamic Theory of Irreversible Processes. II. Sedimentation Equilibrium of Fluids in Gravitational and Centrifugal Fields. American Journal of Physics, 24, 535-561.              eww150126lx

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