跳至主要内容

Generalized Electron Balance for Dynamic Redox Systems in Mixed-Solvent Media

Read full paper at:
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=52018#.VH5qpWfHRK0

A complex example of electrolytic redox system involving 47 species, 3 electron-active elements and five (3 am-phiprotic + 2 aprotic) co-solvents, is presented. Mixed solvates of the species thus formed are admitted in the system considered. It is proved that the Generalized Electron Balance (GEB) in its simplest form obtained according to the Approach II to GEB is identical with the one obtained for aqueous media and binary-solvent system, and is equivalent to the Approach I to GEB.
Cite this paper
Michałowska-Kaczmarczyk, A. and Michałowski, T. (2014) Generalized Electron Balance for Dynamic Redox Systems in Mixed-Solvent Media. Journal of Analytical Sciences, Methods and Instrumentation, 4, 102-109. doi: 10.4236/jasmi.2014.44014.
 

[1] http://quoteinvestigator.com/2011/05/13/einstein-simple/
[2] Michalowski, T., Toporek, M., Michalowska-Kaczmarczyk, A.M. and Asuero, A.G. (2013) New Trends in Studies on Electrolytic Redox Systems. Electrochimica Acta, 109, 519-531.
http://dx.doi.org/10.1016/j.electacta.2013.07.125
[3] Michalowski, T., Michalowska-Kaczmarczyk, A.M. and Toporek, M. (2013) Formulation of General Criterion Distinguishing between Non-Redox and Redox Systems, Electrochimica Acta, 112, 199-211.
http://dx.doi.org/10.1016/j.electacta.2013.08.153
[4] Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2013) Comparative Balancing of Non-Redox and Redox Electrolytic Systems and Its Consequences. American Journal of Analytical Chemistry, 4, 46-53.
http://dx.doi.org/10.4236/ajac.2013.410A1006
[5] Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2014) Compact Formulation of Redox Systems According to GATES/GEB Principles, Journal of Analytical Sciences, Methods and Instrumentation, 4, 39-45.
http://dx.doi.org/10.4236/jasmi.2014.42006
[6] Michalowski, T., Ponikvar-Svet, M., Asuero, A.G. and Kupiec, K. (2012) Thermodynamic and Kinetic Effects Involved with pH Titration of As(III) with Iodine in a Buffered Malonate System. Journal of Solution Chemistry, 41, 436-446. http://dx.doi.org/10.1007/s10953-012-9815-6
[7] Michalowski, T. (2011) Application of GATES and MATLAB for Resolution of Equilibrium, Metastable and Non-Equilibrium Electrolytic Systems, Chapter 1. In: Michalowski, T., Ed., Applications of MATLAB in Science and Engineering, InTech—Open Access Publisher in the Fields of Science, Technology and Medicine, 1-34.
http://www.intechopen.com/books/show/title/applications-of-matlab-in-science-and-engineering
[8] Michalowska-Kaczmarczyk, A.M., Michalowski, T., Asuero, A.G., Rymanowski, M. and Toporek, M. (2014) Formulation of Titration Curves for Some Redox Systems. American Journal of Analytical Chemistry, 5, 861-878.
http://dx.doi.org/10.4236/ajac.2014.513095
[9] Pilarski, B., Dobkowska, A., Foks, H. and Michalowski, T. (2010) Modeling of Acid-Base Equilibria in Binary-Solvent Systems: A Comparative Study. Talanta, 80, 1073-1080.
http://dx.doi.org/10.1016/j.talanta.2009.07.033
[10] Asuero, A.G., Pilarski, B., Dobkowska, A. and Michalowski, T. (2013) On the Isohydricity Concept—Some Comments, Talanta 112, 49-54. http://dx.doi.org/10.1016/j.talanta.2013.03.067
[11] Michalowski, T., Pilarski, B., Asuero, A.G. and Michalowska-Kaczmarczyk, A.M. (2014) Modeling of Acid-Base Properties in Binary-Solvent Systems, Chapter 9.4. In: Wypych. G., Ed., Handbook of Solvents, Vol. 1 Properties, ChemTec Publishing, Toronto, 623-648.                       eww141203lx
标签：

评论

发表评论

此博客中的热门博文

Does Immigration Promote the Investment of the Monopolistic Firm?

In the present paper, we examine the effect of increasing uncertainty of immigrants’ growth on the optimal timing of investment of a firm that has a monopolistic power over the labor market. It is revealed that when the uncertainty of immigrants’ growth is more than a threshold level, increasing uncertainty of immigrants’ growth accelerates the optimal timing of firms’ investment and enhances the economic growth, even if the uncertainty of immigrants’ growth is formulated by the geometric Brownian motion, which is in sharp contrast to the standard result that an increase in the uncertainty postpones the optimal timing. With an increase in the immigrants over the past ten years, workforces in the host countries have been growing significantly to the extent that the immigrants represent 70% of the increase in the workforce in Europe, and 47% in the United States as OECD indicates. In the present paper, we attempted to investigate the effect of increased uncertainty caused by the growi...
发表评论
阅读全文

Education Policy Implementation: A Mechanism for Enhancing Primary Education Development in Zanzibar

Education is one of the fundamental rights of individuals; therefore, the government of a country needs to develop and strengthen educational policy and quality as well as to ensure that everyone has equal access to basic education. The improvement of access and quality of education in the world is becoming as an essential factor in development, whereas the basic education (primary school), is acknowledged as a foundation of the higher educational development for every country. To fulfill this goal, governments introduce several policies and procedures; however, it requires some reforms and participation from the politician, policymakers, and other stakeholders to re-examine educational policy so that it can lead to multiplication and betterment of the reforms. Educational reforms actually focus on accountability. A positive educational development and reform is very challenging and needs more effort and strategy on how to use and utilize the resources effectively as such it can achie...
发表评论
阅读全文