跳至主要内容

Recovering Scrap Anode Copper Using Reactive Electrodialysis

Read full paper at:
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=51368#.VGVbQWfHRK1

Despite functioning without major operational problems—copper electro-refining does not allow complete use of copper anodes, peaking at 85% of the copper anode in weight. Consequently, the remaining 15% of scrap copper must be recirculated into the copper smelting. The use of reactive electrodyalysis is a system capable of continuously electro-refining scrap, by using a stainless steel basket and a cationic exchanging membrane in order to increase production of copper cathodes at the same percentage; it currently today returns to the copper smelter. In terms of specific energy consumption, this process would use between 3 and 4 times the value of normal electro-refining.
Cite this paper
Cifuentes, G. , Hernández, J. and Guajardo, N. (2014) Recovering Scrap Anode Copper Using Reactive Electrodialysis. American Journal of Analytical Chemistry, 5, 1020-1027. doi: 10.4236/ajac.2014.515108
 

[1] Cifuentes, G., Vargas, C. and Simpson, J. (2009) Analysis of the Main Variables That Influence the Cathodic Rejection during Copper Electrorefining (Análisis de las principales variables que influyen en el rechazo catódico durante el electrorrefino del cobre). Revista de Metalurgia, 45, 228-236.
http://dx.doi.org/10.3989/revmetalm.0729
[2] Davenport, G., King, M., Schlesinger, M. and Biswas, A.K. (2002) Extractive Metallurgy of Copper. 3rd Edition, Elsevier, Oxford.
[3] Hartinger, L. (1990) Handbook of Effluent Treatment and Recycling for the Metal Finishing Industry. 2nd Edition, Carl Hanser, Munich.
[4] Di Bari, G. (2000) Nickel Plating. Metal Finishing, 98, 270-288.
http://dx.doi.org/10.1016/S0026-0576(00)80334-7
[5] Chena, S.-S., Lib, C.-W., Hsua, H.-D., Leeb, P.-C., Changa, Y.-M. and Yang, C.-H. (2009) Concentration and Purification of Chromate from Electroplating Wastewater by Two-Stage Electrodialysis Processes. Journal of Hazardous Materials, 161, 1075-1080.
http://dx.doi.org/10.1016/j.jhazmat.2008.04.106
[6] Llorens, J. (1992) Membranes Technology (Tecnología de Membranas). Class Notes, University of Barcelona, Barcelona.
[7] Schirg, P.G. (2010) Introduction to Theory and Practice in Technical Membranes (Introducción a la teoría y práctica de la Técnica de Membranas). PS Prozesstechnike GMBH.
www.membran.com
[8] Koter, S. and Warszawski, A. (2000) Electromembrane Processes in Environment Protection. Polish Journal of Environmental Studies, 9, 45-56.
[9] Xu, T.W. (2005) Ion Exchange Membranes: State of Their Development and Perspective. Journal of Membrane Science, 263, 1-29.
http://dx.doi.org/10.1016/j.memsci.2005.05.002
[10] Baker, R.W. (2004) Chapter 10: Ionic Exchange Membranes in Electro-Dialysis Processes. In: Membrane Technology and Applications, 2nd Edition, John Wiley Sons, Ltd., Hoboken.
http://dx.doi.org/10.1002/0470020393.ch10
[11] Bernardes, A.M., Siqueira, M.A. and Zoppas, J. (2013) Electrodialysis and Water Reuse: Novel Approaches—Topics in Mining, Metallurgy and Materials Engineering. Springer, Berlin-Heidelberg.
[12] Herrera, C. (2003) Electrolytic Refining of Particulate Anodicshot (Refinación electrolítica de scrap anódico granallado). Titulation Work, Metallurgical Department, University of Santiago of Chile, Santiago.
[13] Urra, C. (2003) Electrolytic Refining of Particulate Anodic Scrap (Refinación electrolítica de scrap anódico particulado). Titulation Work, Metallurgical Department, University of Santiago of Chile, Santiago.
[14] Cifuentes, G., Simpson, J., Lobos, F., Briones, L. and Morales, A. (2009) Copper Electrowinning Based on Ractive Electrodialysis. Journal of the Chilean Chemical Society, 54, 334-338.
http://dx.doi.org/10.4067/S0717-97072009000400002              eww141114lx

评论

此博客中的热门博文

Does Immigration Promote the Investment of the Monopolistic Firm?

In the present paper, we examine the effect of increasing uncertainty of immigrants’ growth on the optimal timing of investment of a firm that has a monopolistic power over the labor market. It is revealed that when the uncertainty of immigrants’ growth is more than a threshold level, increasing uncertainty of immigrants’ growth accelerates the optimal timing of firms’ investment and enhances the economic growth, even if the uncertainty of immigrants’ growth is formulated by the geometric Brownian motion, which is in sharp contrast to the standard result that an increase in the uncertainty postpones the optimal timing. With an increase in the immigrants over the past ten years, workforces in the host countries have been growing significantly to the extent that the immigrants represent 70% of the increase in the workforce in Europe, and 47% in the United States as OECD indicates. In the present paper, we attempted to investigate the effect of increased uncertainty caused by the growi...

Education Policy Implementation: A Mechanism for Enhancing Primary Education Development in Zanzibar

Education is one of the fundamental rights of individuals; therefore, the government of a country needs to develop and strengthen educational policy and quality as well as to ensure that everyone has equal access to basic education. The improvement of access and quality of education in the world is becoming as an essential factor in development, whereas the basic education (primary school), is acknowledged as a foundation of the higher educational development for every country. To fulfill this goal, governments introduce several policies and procedures; however, it requires some reforms and participation from the politician, policymakers, and other stakeholders to re-examine educational policy so that it can lead to multiplication and betterment of the reforms. Educational reforms actually focus on accountability. A positive educational development and reform is very challenging and needs more effort and strategy on how to use and utilize the resources effectively as such it can achie...