Photocatalytic Activity of Anodized Titanium Sheets under Ultra-Violet and Visible Light Irradiation
Read full paper at:
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=50961#.VFCKMFfHRK0
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=50961#.VFCKMFfHRK0
Author(s)
A commercially pure titanium sheet precipitated TiC
in the surface layer was fabricated by anodic oxidation in NH4NO3
solution and heat treatment in air. The fabricated sheet showed
relatively high photocatalytic activity in 0.1 M KI solution, which was
close to the activity level of the P-25 particle made by Degussa
Corporation. It exhibited photocatalytic activity in antifungal and
antivirus tests under black light irradiation. The better photocatalytic
activity under black light irradiation is considered to be related to
the formation of anatase and rutile type titanium dioxides and rough
surface. It also showed photocatalytic activity under visible light
irradiation, which is considered to be attributable to carbon and
nitrogen doping in titanium dioxide.
Cite this paper
Kaneko, M. , Tokuno, K. , Yamagishi, K. , Wada, T.
and Hasegawa, T. (2014) Photocatalytic Activity of Anodized Titanium
Sheets under Ultra-Violet and Visible Light Irradiation. Journal of Surface Engineered Materials and Advanced Technology, 4, 369-378. doi: 10.4236/jsemat.2014.46041.
| [1] |
Akira, F. and Kenichi, H. (1972)
Electrochemical Photolysis of Water at a Semiconductor Electrode.
Nature, 238, 37-38. http://dx.doi.org/10.1038/238037a0 |
| [2] |
Ralph, W.M. (1987)
Photooxidation of Organic Impurities in Water Using Thin Films of
Titanium Dioxide. Journal of Physical Chemistry, 91, 3328-3333. http://dx.doi.org/10.1021/j100296a044 |
| [3] |
Yoshihisa, O., Kazuhito, H. and
Akira, F. (1997) Kinetics of Photocatalytic Reaction under Extreamly
Low-Intensity UV Illumination on Titanium Dioxide Thin Films. Journal of
Physical Chemistry, A101, 8057-8062. http://dx.doi.org/10.1021/jp972002k |
| [4] |
Jimmy, C., Yu, Wingkei, H., Jun,
L., Hoyin, Y. and Po, K.W. (2003) Photocatalytic Activity,
Antibacterial Effect, and Photoinduced Hydrophilicity of TiO2 Films
Coated on a Stainless Steel Substrate. Environmental Science and
Technology, 37, 2296-2301. http://dx.doi.org/10.1021/es0259483 |
| [5] |
Yoshihisa, O., Yuki, S., Akira,
F. and Yoshinobu, K. (2008) Self-Sterilization Using Silicone Catheters
Coated with AG and TiO2 Nanocomposite Thin Film. Journal of Biomedical
Materials Research, 85B, 453-460. http://dx.doi.org/10.1002/jbm.b.30965 |
| [6] |
Kinji, O. and Susumu, Y. (2007)
Effect of Electrolysis Conditions on Photocatalytic Activities of the
Anodized TiO2 Films. Journal of Solid State Chemistry, 180, 3425-3433. http://dx.doi.org/10.1016/j.jssc.2007.10.003 |
| [7] |
Naofumi, O., Shinji, K. and
Kenji, K. (2013) Effect of Electrolytes on Anodic Oxidation of Titanium
for Fabricating Titanium Dioxide Photocatalyst. Thin Solid Films, 534,
70-75. http://dx.doi.org/10.1016/j.tsf.2013.01.106 |
| [8] |
Yoshiteru, M., Naofumi, O.,
Satoshi, S. and Naoya, M. (2009) Visible Light Response of Sulfur-Doped
Rutile Dioxide Photocatalysts Fabricated by Anodic Oxidation. Applied
Catalysis, B91, 152-156. http://dx.doi.org/10.1016/j.apcatb.2009.05.018 |
| [9] |
Naofumi, O., Hirotaka, K.,
Shinji, K., Yoshiteru, M. and Naoya, M. (2013) Fabrication of
Visible-Light-Responsive Titanium Dioxide Layer on Titanium Using Abodic
Oxidation in Nitric Acid. Applied Surface Science, 270, 513-518. http://dx.doi.org/10.1016/j.apsusc.2013.01.071 |
| [10] | Michio, K., Kazuhiro, T., Teruhiko, H., Izumi, M. and Kiyonori, T. (2002) Environmental and Metallurgical Factors Affecting Discoloration of Titanium Sheets in Atmospheric Environments. Proceeding of the 15th International Corrosion Congress, Granada, Paper No. 26. |
| [11] |
Michio, K., Masao, K. and
Kiyonori, T. (2010) Effects of Titanium Carbide (TiC) and Anodizing
Voltages on Discoloration Resistance of Colored-Titanium Sheets.
Corrosion Science, 52, 1889-1896. http://dx.doi.org/10.1016/j.corsci.2010.02.042 |
| [12] |
Harvey, P.R. and Rudham, R.
(1988) Photocatalytic Oxidation of Iodide Ions by Titanium Dioxide.
Journal of the Chemical Society, Faraday Transactions 1: Physical
Chemistry in Condensed Phases, 84, 4181-4190. http://dx.doi.org/10.1039/f19888404181 |
| [13] | Japanese Industrial Standard (2008) Test Method for Antifungal Activity of Photocatalytic Products under Photo Irradiation, JIS R 1705. |
| [14] | Japanese Industrial Standard (2006) Test Method for Antibacterial Activity of Photocatalytic Products under Photo Irradiation and Efficacy, JIS R 1702. |
| [15] |
Roger, I.B., Teresita, G.C.,
John, S.L., Leonardo, P. and Richard, J.D.T. (1991) A Structural
Investigation of Titanium Dioxide Photocatalysts. Journal of Solid State
Chemistry, 92, 178-190. http://dx.doi.org/10.1016/0022-4596(91)90255-G |
| [16] |
Michael, R.H., Scot, T.M.,
Wonyong, C. and Detlef, W.B. (1995) Environmental Application of
Semiconductor Photocatalysis. Chemical Reviews, 95, 69-96. http://dx.doi.org/10.1021/cr00033a004 |
| [17] |
Ryoji, A., Takeshi, M., Takeshi,
O., Koyu, A. and Yasunori, T. (2001) Visible-Light Photocatalysis in
Notrogen-Doped Titanium Oxide. Science, 293, 269-271. http://dx.doi.org/10.1126/science.1061051 eww141029lx |
评论
发表评论