跳至主要内容

Photocatalytic Activity of Anodized Titanium Sheets under Ultra-Violet and Visible Light Irradiation

Read full paper at:
http://www.scirp.org/journal/PaperInformation.aspx?PaperID=50961#.VFCKMFfHRK0

A commercially pure titanium sheet precipitated TiC in the surface layer was fabricated by anodic oxidation in NH4NO3 solution and heat treatment in air. The fabricated sheet showed relatively high photocatalytic activity in 0.1 M KI solution, which was close to the activity level of the P-25 particle made by Degussa Corporation. It exhibited photocatalytic activity in antifungal and antivirus tests under black light irradiation. The better photocatalytic activity under black light irradiation is considered to be related to the formation of anatase and rutile type titanium dioxides and rough surface. It also showed photocatalytic activity under visible light irradiation, which is considered to be attributable to carbon and nitrogen doping in titanium dioxide.
Cite this paper
Kaneko, M. , Tokuno, K. , Yamagishi, K. , Wada, T. and Hasegawa, T. (2014) Photocatalytic Activity of Anodized Titanium Sheets under Ultra-Violet and Visible Light Irradiation. Journal of Surface Engineered Materials and Advanced Technology, 4, 369-378. doi: 10.4236/jsemat.2014.46041
 

[1] Akira, F. and Kenichi, H. (1972) Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature, 238, 37-38.
http://dx.doi.org/10.1038/238037a0
[2] Ralph, W.M. (1987) Photooxidation of Organic Impurities in Water Using Thin Films of Titanium Dioxide. Journal of Physical Chemistry, 91, 3328-3333.
http://dx.doi.org/10.1021/j100296a044
[3] Yoshihisa, O., Kazuhito, H. and Akira, F. (1997) Kinetics of Photocatalytic Reaction under Extreamly Low-Intensity UV Illumination on Titanium Dioxide Thin Films. Journal of Physical Chemistry, A101, 8057-8062.
http://dx.doi.org/10.1021/jp972002k
[4] Jimmy, C., Yu, Wingkei, H., Jun, L., Hoyin, Y. and Po, K.W. (2003) Photocatalytic Activity, Antibacterial Effect, and Photoinduced Hydrophilicity of TiO2 Films Coated on a Stainless Steel Substrate. Environmental Science and Technology, 37, 2296-2301.
http://dx.doi.org/10.1021/es0259483
[5] Yoshihisa, O., Yuki, S., Akira, F. and Yoshinobu, K. (2008) Self-Sterilization Using Silicone Catheters Coated with AG and TiO2 Nanocomposite Thin Film. Journal of Biomedical Materials Research, 85B, 453-460.
http://dx.doi.org/10.1002/jbm.b.30965
[6] Kinji, O. and Susumu, Y. (2007) Effect of Electrolysis Conditions on Photocatalytic Activities of the Anodized TiO2 Films. Journal of Solid State Chemistry, 180, 3425-3433.
http://dx.doi.org/10.1016/j.jssc.2007.10.003
[7] Naofumi, O., Shinji, K. and Kenji, K. (2013) Effect of Electrolytes on Anodic Oxidation of Titanium for Fabricating Titanium Dioxide Photocatalyst. Thin Solid Films, 534, 70-75.
http://dx.doi.org/10.1016/j.tsf.2013.01.106
[8] Yoshiteru, M., Naofumi, O., Satoshi, S. and Naoya, M. (2009) Visible Light Response of Sulfur-Doped Rutile Dioxide Photocatalysts Fabricated by Anodic Oxidation. Applied Catalysis, B91, 152-156.
http://dx.doi.org/10.1016/j.apcatb.2009.05.018
[9] Naofumi, O., Hirotaka, K., Shinji, K., Yoshiteru, M. and Naoya, M. (2013) Fabrication of Visible-Light-Responsive Titanium Dioxide Layer on Titanium Using Abodic Oxidation in Nitric Acid. Applied Surface Science, 270, 513-518.
http://dx.doi.org/10.1016/j.apsusc.2013.01.071
[10] Michio, K., Kazuhiro, T., Teruhiko, H., Izumi, M. and Kiyonori, T. (2002) Environmental and Metallurgical Factors Affecting Discoloration of Titanium Sheets in Atmospheric Environments. Proceeding of the 15th International Corrosion Congress, Granada, Paper No. 26.
[11] Michio, K., Masao, K. and Kiyonori, T. (2010) Effects of Titanium Carbide (TiC) and Anodizing Voltages on Discoloration Resistance of Colored-Titanium Sheets. Corrosion Science, 52, 1889-1896.
http://dx.doi.org/10.1016/j.corsci.2010.02.042
[12] Harvey, P.R. and Rudham, R. (1988) Photocatalytic Oxidation of Iodide Ions by Titanium Dioxide. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 84, 4181-4190.
http://dx.doi.org/10.1039/f19888404181
[13] Japanese Industrial Standard (2008) Test Method for Antifungal Activity of Photocatalytic Products under Photo Irradiation, JIS R 1705.
[14] Japanese Industrial Standard (2006) Test Method for Antibacterial Activity of Photocatalytic Products under Photo Irradiation and Efficacy, JIS R 1702.
[15] Roger, I.B., Teresita, G.C., John, S.L., Leonardo, P. and Richard, J.D.T. (1991) A Structural Investigation of Titanium Dioxide Photocatalysts. Journal of Solid State Chemistry, 92, 178-190.
http://dx.doi.org/10.1016/0022-4596(91)90255-G
[16] Michael, R.H., Scot, T.M., Wonyong, C. and Detlef, W.B. (1995) Environmental Application of Semiconductor Photocatalysis. Chemical Reviews, 95, 69-96.
http://dx.doi.org/10.1021/cr00033a004
[17] Ryoji, A., Takeshi, M., Takeshi, O., Koyu, A. and Yasunori, T. (2001) Visible-Light Photocatalysis in Notrogen-Doped Titanium Oxide. Science, 293, 269-271.
http://dx.doi.org/10.1126/science.1061051                 eww141029lx

评论

此博客中的热门博文

Does Immigration Promote the Investment of the Monopolistic Firm?

In the present paper, we examine the effect of increasing uncertainty of immigrants’ growth on the optimal timing of investment of a firm that has a monopolistic power over the labor market. It is revealed that when the uncertainty of immigrants’ growth is more than a threshold level, increasing uncertainty of immigrants’ growth accelerates the optimal timing of firms’ investment and enhances the economic growth, even if the uncertainty of immigrants’ growth is formulated by the geometric Brownian motion, which is in sharp contrast to the standard result that an increase in the uncertainty postpones the optimal timing. With an increase in the immigrants over the past ten years, workforces in the host countries have been growing significantly to the extent that the immigrants represent 70% of the increase in the workforce in Europe, and 47% in the United States as OECD indicates. In the present paper, we attempted to investigate the effect of increased uncertainty caused by the growi...

Education Policy Implementation: A Mechanism for Enhancing Primary Education Development in Zanzibar

Education is one of the fundamental rights of individuals; therefore, the government of a country needs to develop and strengthen educational policy and quality as well as to ensure that everyone has equal access to basic education. The improvement of access and quality of education in the world is becoming as an essential factor in development, whereas the basic education (primary school), is acknowledged as a foundation of the higher educational development for every country. To fulfill this goal, governments introduce several policies and procedures; however, it requires some reforms and participation from the politician, policymakers, and other stakeholders to re-examine educational policy so that it can lead to multiplication and betterment of the reforms. Educational reforms actually focus on accountability. A positive educational development and reform is very challenging and needs more effort and strategy on how to use and utilize the resources effectively as such it can achie...